Research on Indoor Experimental Technology of ultra-high Temperature Acidizing Corrosion Inhibitors Containing N-Heterocyclic Quaternary Ammonium Salts

Xinghua Zhang; Guangfeng Chen; Hongjing Zhang; Wengang Ding; Qiang Zhang

doi:10.47297/taposatWSP2633-456905.20250604

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Research on Indoor Experimental Technology of ultra-high Temperature Acidizing Corrosion Inhibitors Containing N-Heterocyclic Quaternary Ammonium Salts

Volume 6, Issue 4

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Research on Indoor Experimental Technology of ultra-high Temperature Acidizing Corrosion Inhibitors Containing N-Heterocyclic Quaternary Ammonium Salts
Research on Indoor Experimental Technology of ultra-high Temperature Acidizing Corrosion Inhibitors Containing N-Heterocyclic Quaternary Ammonium Salts
1.Engineering Technology Operation Center of Tianjin Branch of CNOOC (China) Co., Ltd., Tianjin, 300452, China
2.Oilfield Production Division of CNOOC Oilfield Services Co., Ltd., Tianjin, 300452, China
Vol. 6, Issue 4, Pages: 28-39(2025)
Published：22 April 2025
DOI：10.47297/taposatWSP2633-456905.20250604
Accepted：

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Zhang Xinghua,Chen Guangfeng,Zhang Hongjing,et al.Research on Indoor Experimental Technology of ultra-high Temperature Acidizing Corrosion Inhibitors Containing N-Heterocyclic Quaternary Ammonium Salts[J].Theory and Practice of Science and Technology,2025,06(04):28-39.
DOI：

Zhang Xinghua,Chen Guangfeng,Zhang Hongjing,et al.Research on Indoor Experimental Technology of ultra-high Temperature Acidizing Corrosion Inhibitors Containing N-Heterocyclic Quaternary Ammonium Salts[J].Theory and Practice of Science and Technology,2025,06(04):28-39. DOI： 10.47297/taposatWSP2633-456905.20250604.

摘要

Abstract

In the process of acid operation

especially in ultrahigh-temperature wells

metal components such as well bore tubing and surface equipment are severely corroded by acid fluids

leading to operational challenges in oilfield production. At present

the addition of corrosion inhibitors is one of the most effective methods to mitigate metal corrosion. Pyridine residues

quinoline quaternary ammonium salts

aldehyde ketone amine condensates

acetylenic methyl ammonia and imidazoline corrosion inhibitors have been widely studied in industry. Among them

quaternary ammonium salts are widely used in oilfield production because of their excellent corrosion resistance

low toxicity and good water solubility. However

their limited heat resistance makes them unsuitable for ultra deep exploration wells or scientific research wells. This study focuses on N-heterocyclic quaternary ammonium salt-based corrosion inhibitors (alkyl quinolinium quaternary ammonium salts)

which can withstand temperatures up to 200°C

meeting the requirements of ultra-high temperature wells.

关键词

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references

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