A 3D Heterometallic Coordination Polymer Constructed by Trimeric {[Dy<sub>4</sub>]<sub>4</sub>} Single-Molecule Magnet Units

Hao Gong

doi:10.47297/wspbtsWSP2755-952103.20250402

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A 3D Heterometallic Coordination Polymer Constructed by Trimeric {[Dy<sub>4</sub>]<sub>4</sub>} Single-Molecule Magnet Units

4卷第2期

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A 3D Heterometallic Coordination Polymer Constructed by Trimeric {[Dy₄]₄} Single-Molecule Magnet Units
A 3D Heterometallic Coordination Polymer Constructed by Trimeric {[Dy₄]₄} Single-Molecule Magnet Units
Chongqing Key Laboratory of Green Catalysis Materials and Technology, College of Chemistry and Materials Science, Chongqing, 401331, China
2025年4卷第2期页码：15-20
纸质出版：2025-06-30
DOI：10.47297/wspbtsWSP2755-952103.20250402
Accepted：

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Hao Gong. (2025). A 3D Heterometallic Coordination Polymer Constructed by Trimeric {[Dy₄]₄} Single-Molecule Magnet Units. 分析测试学报, 4(2), 15-20. DOI: 10.47297/wspbtsWSP2755-952103.20250402.

Hao Gong.A 3D Heterometallic Coordination Polymer Constructed by Trimeric {[Dy,₄],₄} Single-Molecule Magnet Units[J].Biomedical Testing & Sensing,2025,04(02):15-20. DOI: 10.47297/wspbtsWSP2755-952103.20250402.
Hao Gong. (2025). A 3D Heterometallic Coordination Polymer Constructed by Trimeric {[Dy₄]₄} Single-Molecule Magnet Units. 分析测试学报, 4(2), 15-20. DOI: 10.47297/wspbtsWSP2755-952103.20250402. DOI：

Hao Gong.A 3D Heterometallic Coordination Polymer Constructed by Trimeric {[Dy,₄],₄} Single-Molecule Magnet Units[J].Biomedical Testing & Sensing,2025,04(02):15-20. DOI: 10.47297/wspbtsWSP2755-952103.20250402. DOI：

摘要

Abstract

By making the most of the structural variability of copper cyanide system as 3d motifs

a three-dimensional 3d-4f heterometallic coordination polymer (HCP) formulated as [Dy4Cu7(ina)8(CN)6(OH)5(H2O)5

]

·7H2O

(compound

) has been hydrothermally synthesized and structurally characterized. In compound

[Dy

]

cubane clusters was introduced as secondary building units (SUBs) into the three dimensional architecture. These paired [Dy

]

units

[(Dy

)

]

are further connected by isonicotinic acid carboxylic groups to give 4f motifs as 1D infinite chains. Magnetic susceptibility results indicate that compound

exhibits slow magnetic relaxation.

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Keywords

references

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A 3D Heterometallic Coordination Polymer Constructed by Trimeric {[Dy4]4} Single-Molecule Magnet Units

A 3D Heterometallic Coordination Polymer Constructed by Trimeric {[Dy4]4} Single-Molecule Magnet Units

DOI：10.47297/wspbtsWSP2755-952103.20250402

摘要

Abstract

关键词

Keywords

references

A 3D Heterometallic Coordination Polymer Constructed by Trimeric {[Dy₄]₄} Single-Molecule Magnet Units

A 3D Heterometallic Coordination Polymer Constructed by Trimeric {[Dy₄]₄} Single-Molecule Magnet Units